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 姓 名

 李正義

 性別

 男

 出生年月

 1979.8

 職稱

 副教授

 

單 位

 常州大學(xué)石油化工學(xué)院

 政治面貌

 中共黨員

 所屬學(xué)位點

 有機(jī)化學(xué)

研究方向

 有機(jī)合成

 超分子化學(xué)

 不對稱合成及催化

學(xué)校及

社會兼職

 石油化工學(xué)院教學(xué)辦公室主任

主要從事《有機(jī)化學(xué)》、《有機(jī)化學(xué)實驗》課程的教學(xué)和本科生、碩士研究生畢業(yè)論文指導(dǎo)工作。

 

1、   基于杯芳烴平臺的手性超分子催化劑的設(shè)計、合成及其催化的不對稱反應(yīng)研究，國家自然科學(xué)基金（21002009）

2、   可調(diào)控降解的軸手性高分子材料的研發(fā)，江蘇省高校自然科學(xué)研究重大項目（12KJA150002）

3、   超分子催化手性醫(yī)藥中間體的合成，常州市科技項目（CJ20115019）

4、   手性杯[4]芳烴的合成及其在不對稱催化和分子識別中的應(yīng)用，常州大學(xué)項目（ZMF10020002）

 

1.        Zhengyi Li, Ling Ge, Liang Chen, Qiu-Zheng Tang, Lin-Lin Jin and Xiaoqiang Sun, Synthesis and Crystal Structure of 3,9-Bis(pyridin-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Chinese J. Struct. Chem.2012, 31(5), 728-732.

2.        Zheng-Yi Li, Jia-Wen Chen, Ying Liu, Wei Xia, Leyong Wang, The Use of Calixarene in Asymmetric Catalysis. Curr. Org. Chem. 2011, 15, 39–61.

3.        Zheng-Yi Li, Huaijie Xing, Guoli Huang, Xiaoqiang Sun, Juli Jiang, Leyong Wang, Novel supramolecular organocatalysts of hydroxyprolinamide based on calix[4]arene scaffold for the enantioselective Biginelli reaction. Sci China Chem, 2011, 54(11), 1726-1734.

4.        Yang-Fan Guan, Zheng-Yi Li, Meng-Fei Ni, Chen Lin, Juli Jiang, Yi-Zhi Li, and Leyong Wang, Chiral Moieties-Oriented Single-Stranded Helical Assembly of Calix[4]azacrown Derivatives. Cryst. Growth Des., 2011, 11 (7), 2684–2689.

5.        Zhengyi Li, Beibei Zhou, Liang Chen, Ling Ge and Xiaoqiang Sun, rac-3,9-Bis(3-chlorophenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2011, E67, o2672.

6.        Xin Chen, Zhengyi Li, Xiaoqiang Sun, Hongzhao Ma, Xiaoxin Chen, Jie Ren, Kun Hu, New method for synthesis of sulforaphane and the related isothiocyanates. Synthesis2011, 3991–3996.

7.        Zheng-Yi Li, Cheng-Xi Lu, Guoli Huang, Jie-Jie Ma, Hongsheng Sun, Leyong Wang, Yi Pan, Novel Prolinamide Organocatalysts Based on Calix[4]arene Scaffold for the Enantioselective Direct Aldol Reaction. Lett. Org. Chem.2010, 7, 461–466.

8.        Zhengyi Li, Liang Chen, Qiuzheng Tang and Xiaoqiang Sun, 3,9-Di-tert-butyl-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o3368.

9.        Xiaoqiang Sun, Liang Chen, Yan Jiang and Zhengyi Li*,3,3,9,9-Tetraphenyl-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o3035. (4/4)

10.     Zhengyi Li, Qiuzheng Tang, Kang Wu, Shuling Yu and Xiaoqiang Sun, 3,9-Bis(2,4-dichlorophenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane. Acta Cryst.2010, E66, o1864.

11.     Xiaoqiang Sun, Shu-Ling Yu, Zheng-Yi Li, Yang Yang, Crystal X-ray diffraction guided NMR analysis of 3,9-diaryl-2,4,8,10-tetraoxaspiro[5.5]undecanes under differently shielding effect of terminal aromatic rings. J. Mol. Struct.2010, 973, 152–156.

12.     Qi Meng, Juan-Juan Chen, Zheng-Yi Li, Dan-Feng Li, Gui-Yong Wu and Xiao-Qiang Sun, Synthesis and special structure of a novel low-generation amide dendrimer with pseudo-symmetric branch distribution. J. Chem. Res.2010, 432–434.

13.     Zheng-YiLi,Jia-Wen Chen, Leyong Wang, Yi Pan, Highly Enantioselective Direct Aldol Reaction Catalyzed by Proline Based on Calix[4]arene Scaffold in the Presence of Water. Synlett2009, 2356–2360.

14.     Zheng-YiLi, Ming-Yu Teng, Jie-Jie Ma, Ji Huang, Leyong Wang, Yi Pan, Unprecedented Synthesis of Chiral Calix[4](Aza)Crowns and Potent Encapsulating Methanol. Sci China Ser B-Chem2009, 52, 497–504.

15.     Zheng-YiLi, Jie-Jie Ma, Jia-Wen Chen, Yi Pan, Juli Jiang, Leyong Wang, High-performance Liquid Chromatography Study of the Nitration Course of Tetrabutoxycalix[4]arene at the Upper Rim: Determination of the Optimum Conditions for the Preparation of 5,11,17-Trinitro-25,26,27,28-tetrabutoxycalix[4]arene. Chin. J. Chem.2009, 27, 2031–2036.

16.     Zhengyi Li, Dinghao Yuan, Haitao Xi, Xiaoqiang Sun, 25,26,27,28-Tetrabutoxy- 5,11,17,23-tetra-tert-butylcalix[4]arene chloroform tetrasolvate dehydrate. Acta Cryst.2009, E65, o1697.

 

1、   李正義,馬鴻釗，陳新，孫小強(qiáng)，何向前，一種制備異硫氰酸酯的方法，CN201110420441.3

2、   陳新，孫小強(qiáng)，李正義，任杰，胡昆，蘿卜硫素的合成方法，CN201110162525.1

 

2011中國石油和化學(xué)工業(yè)聯(lián)合會科技進(jìn)步二等獎（2011JBR0476-2-6）.